Here's an example Java program that demonstrates how to access elements from a LinkedList:

import java.util.LinkedList;

public class LinkedListExample {
    public static void main(String[] args) {
        // Create a LinkedList
        LinkedList<String> list = new LinkedList<>();

        // Add elements to the LinkedList
        list.add("Apple");
        list.add("Banana");
        list.add("Cherry");
        list.add("Date");
        list.add("Elderberry");

        // Access elements by index
        System.out.println("Element at index 0: " + list.get(0));
        System.out.println("Element at index 2: " + list.get(2));

        // Access the first and last elements
        System.out.println("First element: " + list.getFirst());
        System.out.println("Last element: " + list.getLast());

        // Iterate over the elements in the LinkedList
        System.out.println("Iterating over the LinkedList:");
        for (String element : list) {
            System.out.println(element);
        }
    }
}

In this example, we first create a LinkedList of strings and add some elements to it using the add() method.

To access elements in the LinkedList, we can use the get() method, which takes an index as an argument and returns the element at that index.

We can also access the first and last elements of the LinkedList using the getFirst() and getLast() methods.

To iterate over the elements in the LinkedList, we can use a for-each loop. This will loop through each element in the LinkedList and print it to the console.